Cumberland Valley Business Park Association (CVBPA)
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FIGURE 2 SOIL VAPOR SURVEY RESULTS |
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Location |
Location Description |
Measurement |
Calibration |
Office - away from work site |
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Ambient @ Site - start |
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SV-1 |
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SV-2 |
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SV-3 |
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SV-4 |
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SV-5 |
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SV-6 |
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SV-7 |
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SV-8 |
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SV-9 |
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SV-10 |
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SV-11 |
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SV-12 |
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SV-13 |
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SV-14 |
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SV-15 |
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Ambient @ Site - end |
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Attach map if locations are not described.
Site Location: __________________________________ Date: _____________________
Notes: ______________________________________________________________________ ____________________________________________________________________________
____________________________________________________________________________
Surveyed by: ________________________________________________________________
2.1.3 Soil Sampling
If soil vapor survey results are less than 10 parts per million (ppm) above ambient readings at the work area, no soil sample or further monitoring will be needed and the Health and Safety Plan (HASP) will not be applicable to subsequent intrusive activities at the work area. If the soil vapor results are less than 100 ppm, but exceed 10 ppm, no soil sample will be required. Work cannot proceed, however, unless the following conditions are met:
A soil sample should be collected where soil vapor readings are in excess of 100 ppm or if visibly stained soils or product are noted. A borehole or test pit should be advanced to the depth of the final excavation and soils screened with a flame-ionization detector (FID) or photo ionization detector (PID). The soil with the highest FID or PID detection (or if no distinct zone is encountered, from total depth) should be tested for Target Compound List (TCL) volatile organics with location and concentration documented in the Administration Record on Form 1.
If the sampling results exceed PADEP Act 2 direct contact standards, LIDA and the LEAD Environmental Coordinator should be contacted and excavation halted until the situation is assessed.
If the results do not exceed DEP standards and no further investigation is necessary, the results should be compiled and placed in the Administrative Record with a copy supplied to LIDA following excavation.
2.1.4 Emergency Excavating
There will be occasions where there is no time to wait for soil sample results. Prior to excavating, utility and soil vapor surveys will still be required.
If the soil vapor survey measures organic vapors that exceed 10 ppm above ambient, work cannot proceed unless the following conditions are met:
If breathing zone measurements of organic vapors exceed 100 ppm at any time, work shall be immediately halted and the workers removed from the exclusion zone. Work may not proceed until:
2.2 Preconstruction and Predevelopment Activities
2.2.1 Site Contamination Assessment - Phase I
A Site Contamination Assessment (SCA) is required for any major construction activity or development of new buildings. The Phase I SCA will not require Army approval. Each SCA will consist of the following work activities:
Perform a site reconnaissance of the grounds and buildings at each location. The site reconnaissance consists of a walkover to observe the physical characteristics, conditions, and daily operations of the facility. In particular, perform close examination of the site buildings, surficial soils, and cover materials for evidence of possible existing contamination such as surface stains, odors, and stressed vegetation.
2.2.2 Minimum Sampling Requirements
A minimum of one soil sample will be collected and analyzed for Target Compound List (TCL) volatiles if soil survey results exceed 10 ppm above ambient levels or if stained soils or product are noted. This preliminary sample will serve to screen for the presence of contaminants near or above the regulatory thresholds.
Within the area of excavation, the preliminary soil sample location should be based upon the results of visual inspection, soil vapor survey and the SCA. If no soil vapor anomaly is detected, the soil sample location should be placed at the center of the excavation. For large excavation areas, one sample location per acre up to a total of five sample locations will be collected. The formal sampling requirements of SW-846 (EPA, Test Methods for Evaluating Solid Waste - Physical/Chemical Methods EPA SW-846, 1984) are not necessary for preliminary sampling. Sample depths for the various analyses are discussed in Section 2.5.
2.3 Site Contamination Assessment - Phase II
If the sampling plan investigation detects TCL materials that exceed PADEP's statewide health standards the following procedures should be followed:
A.) Report to LIDA and Army Environmental Coordinator.
B.) Assess Situation.
1) Are there any immediate health and safety concerns?
2) Modify or update the Health & Safety Plan, if appropriate.
C.) Formulate a new scope.
1) Terminate or relocate project.
2) If construction is to proceed, additional sampling will be required to identify the vertical and horizontal extent of contamination
2.3.1 Analytical Testing
2.3.1.1 Preliminary Samples - Soils - Preliminary soil samples should be tested for the Target Compound List (TCL) volatiles, Figure 3 in the following manner:
Samples collected by trenching, hand auguring, or drilling should be screened for organic vapors with a PID or FID. The sample with the highest reading should be analyzed for TCL volatile organics. If no organic vapors are detected, obtain the soil sample from the maximum depth of excavation or where stained soils are noted.
Groundwater - If groundwater is encountered, groundwater samples from monitoring wells should be tested for TCL volatile organics. Water in the subsurface that is determined to be perched water over bedrock or recently infiltrated water from a precipitation event is not expected to be contaminated and does not have to be tested. Water contained during intrusive activities should be analyzed for purgeable halocarbons by EPA method 8021B (refer to Section 3.0 on Waste Handling).
FIGURE 3
TARGET COMPOUND LIST
TCL Volatile Organics by GC/MS
Acetone |
Dibromochloromethane |
4-Methyl-2-pentanone (MIBK) |
Benzene |
1,1-Dibromochloromethane |
Styrene |
Bromodichloromethane |
1,2-Dichloroethane |
1,1,2,2-Tetrachloroethane |
Bromoform |
1,1-Dichloroethene |
Tetrachloroethane |
Bromomethane |
trans-1,2-Dichloroethene |
Toluene |
2-Butanone |
1,2-Dichloropropane |
1,1,1-Trichloroethane |
Carbon Disulfide |
cis-1,3-Dichloropropene |
1,1,2-Trichloroethane |
Carbon Tetrachloride |
trans-1,3-Dichloropropene |
Trichloroethene |
Chlorobenzene |
Ethylbenzene |
Vinyl Acetate |
Chloroethane |
2-Hexanone |
Vinyl Chloride |
Chloroform |
Methylene Chloride |
Xylenes, Total |
Chloromethane |
2.3.2 Additional Samples
In subsequent tests, the number of parameters can be reduced based upon preliminary results, site conditions, and approval of PADEP. One soil sample should be collected, its soil classification noted, and evaluated for:
This information can be used to calculate a site-specific soil to groundwater pathway/number value using the equation in the Act 2 regulations at 250.308 (a)(3).
MSCS = MSCGW ((Koc * focC) + 0W/Pb) DF
where: MSCS (mg/kg) = the generic value for a regulated substance in soil
MSCGW (mg/L) = MSC of a regulated substance in groundwater
Koc (L/kg) = organic carbon partition coefficient for a regulated substance
foc = fraction of organic carbon in soil (default value = 0.0025)
0w = water-filled porosity of soil (default value = 0.2)
Pb (kg/L) = dry bulk density of soil (default value = 1.8 kg/l)
DF = dilution factor (default value = 100
2.3.3 Analytical Testing QA/QC
All laboratory analyses must be conducted in accordance with SW-846 procedures and methodologies. Samples must be analyzed by a laboratory certified by PADEP for Volatile Organics.
To insure precision reproducibility and accuracy of preliminary and additional samples submitted for laboratory analysis and field sampling, QA/QC procedures will be followed for Preconstruction/Predevelopment Activities. This will be accomplished through sample blanks and duplicates. Sample blanks are designed to measure any contaminants derived from sampling equipment or acquired during transport. Duplicates are designed to measure laboratory accuracy and overall precision of the sampling program. The exact number of blanks should be defined in the work scope; QA/QC samples will not be required for emergency excavation sampling or on projects where three or fewer samples are collected. The following table lists the types of QA/QC samples:
QA Sample |
Description |
Frequency |
Sample Duplicate |
Soil or water sample split in two and blindly submitted to the laboratory. |
One per 20 samples. |
Field Blank, Water |
Sample generated at the time of sampling. Containers and reagents transported to field and exposed to the same conditions as the samples. |
One blank per day or one blank per 20 samples, whichever is fewer. |
Trip Blank, Water and Soil |
Sample prepared prior to sampling event and carried through sampling without being opened in field. This blank is generated for volatile organics only. |
One per day or one per container. |
Rinsate Blank |
Sample generated by passing DI water over equipment after soil sampling and decontamination. |
One per 20 samples. |
If TCL compounds are detected in QA/QC samples, laboratory procedures must be evaluated for contamination induced during the analysis. Next evaluate whether the detected compound is statistically significant. If all explanations indicate unreliable results, resampling must be done.
3.0 WASTE HANDLING
Before contaminated soil or groundwater are excavated or pumped, LIDA and the Army must approve contingencies made for treatment, storage, or disposal. Any time contaminated soils or groundwater are generated or expected to be generated, storage and handling of this material shall be coordinated with the Director of Public Works. Provisions for treatment or disposal will be considered on a case-by-case basis and are not discussed in this sampling plan.
Waste handling activities must meet the hazardous waste requirements of the EPA (40 CFR) and Pennsylvania Title 25, Chapters 260 to 270.
Three types of soils are anticipated to be potentially encountered during excavation activities: soils with no staining or positive OVM readings that are believed to be uncontaminated; soils with minor amounts of contamination, such as slight staining or moderate OVM readings, and soils with significant evidence of contamination. Soils that are believed to be uncontaminated may be used for backfill at the project site if no contaminated soils were encountered but shall be tested if other contaminated soils are found in the excavation or if they are to be taken off the base. Soils with minor evidence of contamination shall be handled in accordance with Pennsylvania's Residual Waste Regulations found at 25 Pa. Code Chapters 287 and 299. Soils with significant evidence of contamination should be handled as if it were hazardous waste until analytical results are obtained to determine if the material is a characteristic hazardous waste.
Groundwater may also be encountered during drilling or excavation activities. Perched precipitation or shallow groundwater in the hilltop areas underlain by the Martinsburg Formation may not be contaminated with volatile organic compounds, but groundwater in the limestone bedrock over much of the site does contain chlorinated solvents. Groundwater (not perched water) that is produced during intrusive activities shall be handled as if contaminated and contained in drums or portable tanks until it is analyzed for purgeable halocarbons (EPA SW846 test method 8021B). Water that is found to be uncontaminated (levels of volatile organic compounds are below the Pennsylvania Act 2 Standards for groundwater) may be discharged to the local storm water conveyance system after receipt of laboratory results. A copy of the laboratory results shall be furnished to LIDA and the Army. The need to contain water at ongoing project sites where the water is found to be uncontaminated will be resolved with the Army on a case-by-case basis. Contaminated water shall be stored and handled in accordance with the procedures described below. No excavations shall be pumped or dewatered without first contacting the Army.
3.1 Storage
The length of time that regulated materials can be stored on-site without meeting the substantial requirements of a storage facility (required by the 1976 Resource Conservation and Recovery Act [RCRA] in Subtitle C Hazardous Waste Management) is dependent on the quantity and type of waste. For the purposes of storage times, there are two waste types, hazardous (requiring an EPA identification number) and non hazardous. Time extensions can be obtained at the discretion of the EPA regional administrator on a case-by-case basis. Contact the EPA Regional Representative, Mr. William Arguto. The following table lists the storage times and possible extensions:
DETERMINING INTERIM WASTE STORAGE TIME |
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Quantity |
Waste Category |
Storage Time |
Extension |
More than 2,200 pounds per month |
Large quantity generator, hazardous |
90 days |
30 days |
220 to 2,200 pounds per month |
Large quantity generator, hazardous |
180 days |
90 days |
Any amount |
Non hazardous |
1 year |
None |
For a full discussion of storage and container requirements, see 40 CFR Part 265.
For small quantities of soil or liquid wastes, new 55-gallon drums can be used. Drums should be stored in containerized skids or diked areas and managed according to the Hazardous Waste Manual. Rules for use and management of containers are found in 40 CFR 265.170. The stored materials should be examined weekly for leaks and odors. Figure 5 is a sample inspection form.
FIGURE 4
INSPECTION FOR LEAKS HAZARDOUS WASTE STORAGE |
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Week |
Day |
Date |
Inspector |
Comments |
1 |
7 |
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2 |
14 |
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3 |
21 |
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4 |
28 |
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5 |
35 |
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6 |
42 |
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7 |
49 |
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8 |
56 |
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9 |
63 |
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10 |
70 |
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11 |
77 |
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12 |
84 |
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90 |
Maximum Storage Time |
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Inspect each drum and containment structure for leaks. Note presence of odors, corrosion, or staining.
APPENDIX A
APPENDIX B
SITE BACKGROUND INFORMATION FORM
SITE BACKGROUND INFORMATION
Part A
Site Mailing Address: ________________________________________________________
________________________________________________________
________________________________________________________
Normal Facility Hours::_______________________________________________________
Site Contact:______________________________ Title: ___________________________
Telephone: ______________________
Site Map Available?______________________ Location Map Available?____________
Facility Elevation:__________________
Reason for Investigation:_______________________________________________________
___________________________________________________________________________
Facility Size:_________________________________________________________________
Ground Cover:_______________________________________________________________
Water Source:________________________________________________________________
Water Discharge:_____________________________________________________________
Former Facility Uses:__________________________________________________________
___________________________________________________________________________
Proposed Facility Uses:________________________________________________________
___________________________________________________________________________
Nearby Businesses:____________________________________________________________
___________________________________________________________________________
Nearby Residences:___________________________________________________________
___________________________________________________________________________
Known Groundwater Problems:__________________________________________________
___________________________________________________________________________
_________________________________ Expected Depth to Water:____________
Known Vapor Problems:_______________________________________________________
___________________________________________________________________________
Nearby Surface Water:_________________________________________________________
___________________________________________________________________________
_________________________________ Surface Water Elevation:_____________
Geologic Formation:__________________________________________________________
___________________________________________________________________________
_________________________________ Expected Depth to Rock:_____________
Soil Type:___________________________________________________________________
___________________________________________________________________________
SITE BACKGROUND INFORMATION
Part B
Utility Information
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Present |
Contacted |
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Utilities Survey |
Yes |
No |
Yes |
No |
Utility Name |
Phone No. |
Gas |
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Fuel |
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Water |
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Electrical |
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Telephone |
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Video |
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Other |
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Municipality:___________________________ One Call Serial No.:__________________
SITE BACKGROUND INFORMATION
Part C
Site Hazards
Describe Known Site Hazards (include sketch plan)________________________________
_________________________________________________________________________
Suspected Hazards__________________________________________________________
_________________________________________________________________________
Plan to Control Hazards______________________________________________________
_________________________________________________________________________
Personnel Protection Required: A____ B____ C____ D____
Modifications or Specialized Equipment:_________________________________________
_________________________________________________________________________
Detection Equipment:_______________________________________________________
Action Level: ______________________________________________________
______________________________________________________
Action Planned:______________________________________________________
______________________________________________________
Decontamination Procedures:
Personnel:__________________________________________________________
Protective Equipment:________________________________________________
Support Equipment:__________________________________________________
Sampling Equipment:_________________________________________________
Other (describe): ________________________________________________
________________________________________________
Assigned On-Site Personnel |
Task |
Date: Trained |
Physical |
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SITE BACKGROUND INFORMATION
Part D
Hazardous Materials On-Site
Hazardous Material Form: Gas____ Liquid____ Solid____
Containment: Groundwater____ Free Product____ Soils____
Lagoon____ Seep____ Drum____ Other______________
Material Characteristics: Ignitable____ Reactive____
Volatile____ Toxic____ Radioactive____
Hazardous Materials (Add Hazardous Substance Data Sheets for each compound):
Compound |
Concentration |
Warning Properties |
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Plan Approved By (Company official)________________________ Date:_____________
(Signature)
Company Safety Officer___________________________________ Date:_____________
(Signature)